AbstractLand surface temperature (LST) is an important factor in global change studies, heat balance and as control for climate change. A comparative study of LST over parts of the Singhbhum Shear Zone in India was undertaken using various emissivity and temperature retrieval algorithms applied on visible and near infrared (VNIR), and thermal infrared (TIR) bands of high resolution Landsat-7 ETM+ imagery. LST results obtained from satellite data of October 26, 2001 and November 2, 2001 through various algorithms were validated with ground measurements collected during satellite overpass. In addition, LST products of MODIS and ASTER were compared with Landsat-7 ETM+ and ground truth data to explore the possibility of using multi-sensor approach in LST monitoring. An image-based dark object subtraction (DOS3) algorithm, which is yet to be tested for LST retrieval, was applied on VNIR bands to obtain atmospheric corrected surface reflectance images. Normalized difference vegetation index (NDVI) was estimated from VNIR reflectance image. Various surface emissivity retrieval algorithms based on NDVI and vegetation proportion were applied to ascertain emissivities of the various land cover categories in the study area in the spectral range of 10.4–12.5μm. A minimum emissivity value of about 0.95 was observed over the reflective rock body with a maximum of about 0.99 over dense forest. A strong correlation was established between Landsat ETM+ reflectance band 3 and emissivity. Single channel based algorithms were adopted for surface radiance and brightness temperature. Finally, emissivity correction was applied on ‘brightness temperature’ to obtain LST. Estimated LST values obtained from various algorithms were compared with field ground measurements for different land cover categories. LST values obtained after using Valor’s emissivity and single channel equations were best correlated with ground truth temperature. Minimum LST is observed over dense forest as about 26°C and maximum LST is observed over rock body of about 38°C. The estimated LST showed that rock bodies, bare soils and built-up areas exhibit higher surface temperatures, while water bodies, agricultural croplands and dense vegetations have lower surface temperatures during the daytime. The accuracy of the estimated LST was within ±2°C. LST comparison of ASTER and MODIS with Landsat has a maximum difference of 2°C. Strong correlation was found between LST and spectral radiance of band 6 of Landsat-7 ETM+. Result corroborates the fact that surface temperatures over land use/land cover types are greatly influenced by the amount of vegetation present.