The primary mechanisms limiting Li-S (lithium sulfur) cell cycle life and thermal stability are discussed. Two major cycle life limiting mechanisms are identified: development of rough surface morphology on the metallic lithium anode with cycling; and depletion of lithium and electrolyte components through chemical reaction. The approach taken here to mitigate these problems, by employing physical protection, including multi-functional membrane assemblies and non-isotropic pressure is presented. Sulfur utilization of 92%, at C/5 discharge rates, increased cycle life and elimination of thermal runaway in 300 mAh Li-S cells was achieved.


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    Title :

    High energy rechargeable Li-S cells for EV application. Status, remaining problems and solutions


    Additional title:

    Wiederaufladbare Li-S-Hochenergiezellen für die Elektrofahrzeuganwendung. Status, verbleibende Probleme und Lösungen


    Contributors:
    Mikhaylik, y. (author) / Kovalev, I. (author) / Schock, R. (author) / Kumaresan, K. (author) / Xu, J. (author) / Affinito, J. (author)


    Publication date :

    2010


    Size :

    12 Seiten, 13 Bilder, 1 Tabelle, 16 Quellen



    Type of media :

    Conference paper


    Type of material :

    Print


    Language :

    English





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