To develop a practicable and clear guideline for implementing Chevrons on China's highways, it is necessary to understand the effect of Chevrons on driving performance in different roadway geometries. Using a driving simulator, this study tests the effect of China's Chevrons on vehicle speed and lane position on two-lane rural highway horizontal curves with different roadway geometries. The results showed a significant effect of Chevrons on speed reduction, and this function was not significantly affected by curve radius but was statistically affected by curve direction. The speed reduction caused by Chevrons was also significant at the approach of curve, middle of curve and point of tangent. The 85th percentile speed was also markedly lower when Chevrons were present. We also found a significant effect of Chevrons in encouraging participants to drive the vehicle with a more proper lane position at the first half of curves; and this function was slightly affected by curve radius. Meanwhile, the effect of Chevrons on keeping drivers staying in a more stable lane position was also statistically significant at the second half of curves. In sharp curves, the function of Chevrons to make drivers keep a stable lane position was lost. Besides, the impact of curve direction on the function of Chevrons on lane position was always present, and drivers would drive slightly away from Chevrons. Regardless of the curve radius, China's Chevrons at horizontal curves provide an advance warning, speed control and lane position guide for traffic on the nearside of Chevrons. Besides, combing with the function of Chevrons on preventing excessive speed and the benefit to make drivers keep a more proper lane position, China's Chevrons appear to be of great benefit to reduce crashes (e.g., run-off-road) in curves.